Nano-crystals at the interface between two liquids discovered at PETRA III

Liquid on liquid goes solid

Electron density profiles

Top: Electron density profiles for different potentials, corresponding to the best fits to X-ray reflectivity data. Bottom: Schematic structural model of the PbFBr adlayer which is formed between water and mercury. Dashed lines indicate the positions of the two sheets of Pb ions and the topmost Hg layer.

Lisa Diffractometer

LISA, a diffractometer at PETRA III was specially designed to investigate interfaces in liquids.

Not all liquids are mixable. An international team of researchers have investigated chemical processes with atomic resolution at the interface between two such liquids and have made an exciting discovery. During an experiment carried out at DESY, they observed the formation of an ordered crystal of exactly five atomic layers between the two liquids, which acts as a foundation for growing even bigger crystals. The experiment was performed in cooperation with scientists from Kiel University (CAU), Israel, the USA, and DESY. The results have just been published in the renowned scientific journal Proceedings of the National Academy of Science. They may result in new semiconductor and nano-particle production processes.

Everyone knows that oil and water do not mix. However, how the interface between two immiscible liquids behaves on an atomic scale is almost completely unknown up to now as it cannot be investigated at this level by most modern surface science methods. To solve this final piece of the puzzle a research team around Dr. Bridget Murphy and Professor Olaf Magnussen (both Physics Department at Kiel University) use the brilliant X-rays at DESY’s ring accelerator PETRA III. There the LISA diffracometer (Liquid Interfaces Scattering Apparatus), an instrument custom designed for investigating interfaces in liquidsby the physicists from Kiel,deflects the highly focussed X-ray beam onto the liquid sample.


In their latest work the researchers wanted to find out, for the first time, what exactly occurs during chemical growth at liquid interfaces. They investigated mercury in a salt solution containing fluorine, bromine and lead ions and obtained an astonishing result: although the molecules in both liquids were disordered, a nanometre thin layer, that is a ten thousandth of the width of a human hair, with crystalline order formed at their interface. “Our X-ray data show that this layer consists of an atomic layer of fluorine between two layers of lead and bromine”, explains team member Annika Elsen, who just received her doctorate for this work. “Subsequently, larger crystals grow perfectly aligned on top of this nano-layer crystal.”


The atomic order that develops at such disordered liquid interfaces is not only of fundamental interest for science. In fact, in the last few years, a range of chemical processes for producing materials and nano-particles has employed growth at liquid interfaces. For example, two years ago American scientists at the University of Michigan developed a similar process for manufacturing semiconductor germanium with an extremely energy efficient method from its oxide. Further developments of such processes could help to reduce the high energy costs in the production of solar cells. In order to achieve the details of these processes, a better understanding on the atomic scale is required. The work of the Kiel scientists is a first step in this direction.

(from DESY News)

Original publication

In situ x-ray studies of adlayer-induced crystal nucleation at the liquid-liquid interface, A. Elsen, S. Festersen, B. Runge, C.T. Koops, B. M. Ocko, M. Deutsch, O. Seeck, B. M. Murphy, O. M. Magnussen, Proc. Nat. Acad. Sci.,doi: 10.1073/pnas.1301800110(2013)